Compositing LaSrMnO3 perovskite and graphene oxide nanoribbons for highly stable asymmetric electrochemical supercapacitors

Funding Number

45326

Funding Sponsor

Science and Technology Development Fund

Author's Department

Chemistry Department

Second Author's Department

Chemistry Department

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https://doi.org/10.1016/j.mset.2024.10.001

All Authors

Asmaa R. Heiba, Mostafa M. Omran, Rabab M. Abou Shahba, Abdelghaffar S. Dhmees, Fatma A. Taher, Ehab El Sawy

Document Type

Research Article

Publication Title

Materials Science for Energy Technologies

Publication Date

1-1-2025

doi

10.1016/j.mset.2024.10.001

Abstract

The anticipated large contribution of renewable energy resources to the sector of energy production strongly motivated the development of energy storage technologies, of which supercapacitors have drawn a lot of attention. In this work, Lanthanum-Strontium-Manganese-oxide (LSMO) perovskite nanoparticles, graphene oxide nanoribbons (GONRs), and LSMO-GONRs composite were synthesized and tested as electrode materials for supercapacitor applications. The LSMO was synthesized using the co-precipitation/calcination method, while the GONRs were synthesized using the oxidative unzipping of multi-walled carbon nanotubes. The physical/chemical structures were studied using XRD, FT-IR, SEM, TEM, SAED, and XPS. In 1 M KOH, the LSMO-GONRs electrode exhibited a specific capacitance of 490F/g compared to 342F/g and 294F/g for GONRs and LSMO electrodes, respectively, at 1 A/g, showcasing a performance that is not just superior but truly impressive, to the different types of perovskite/carbon-based material composites. The fabricated asymmetric SC device of LSMO-GONRs//GONRs exhibited a potential window of 1.7 V, a specific capacitance of 92.3F/g, an energy density of 38 Wh/kg, and a power density of 860 W/kg at 1 A/g. Moreover, the LSMO-GONRs//GONRs device showed excellent capacity retention and Coulombic efficiency after 10,000 cycles at 10 A/g, revealing the promising employment of LSMO-GONRs composite as a highly stable material for supercapacitor applications.

First Page

82

Last Page

95

Comments

Article. Record derived from SCOPUS.

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