Three-Dimensional Interconnected Binder-Free Mn--Ni--S Nanosheets for High Performance Asymmetric Supercapacitor Devices with Exceptional Cyclic Stability

Author's Department

Physics Department

Second Author's Department

Physics Department

Third Author's Department

Physics Department

Fourth Author's Department

Physics Department

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https://pubs.acs.org/doi/10.1021/acsaem.9b00435

All Authors

Nashaat Ahmed; Basant A. Ali; Mohamed Ramadan; Nageh K. Allam

Document Type

Research Article

Publication Title

ACS Applied Energy Materials

Publication Date

1-1-2019

doi

10.1021/acsaem.9b00435

Abstract

A facile one-step method was demonstrated for the electrodeposition of manganese-nickel sulfide (Mn-Ni-S) 3D interconnected sheets on nickel foam substrates. The as-synthesized materials were characterized using field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) techniques. Upon their use as supercapacitor electrodes, the electrodeposited Mn-Ni-S showed exceptionally high specific capacitance (2849 and 1986 F/g at 1 and 5 A/g, respectively) and an excellent rate capability. Using Fe3O4-GR as the negative electrode and the Mn-Ni-S 3D interconnected sheets as the positive electrode to assemble an asymmetric supercapacitor device revealed high power density (800 W kg-1) and energy density (40.44 Wh kg-1) with 90% capacitance retention and a Columbic efficiency of 100% after 11 000 cycles, indicating the high potential of the fabricated materials for practical energy storage devices.

First Page

3717

Last Page

3725

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