Pyridinium Containing Amide Based Polymeric Ionic Liquids for CO2/CH4 Separation

Author's Department

Chemistry Department

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https://pubs.acs.org/doi/10.1021/acssuschemeng.9b01903

All Authors

Sonia Zulfiqar; Daniele Mantione; Omar El Tall; Fernando Ruipérez; Muhammad Ilyas Sarwar; Alexander Rothenberger; David Mecerreyes

Document Type

Research Article

Publication Title

ACS SUSTAINABLE CHEMISTRY & ENGINEERING

Publication Date

1-1-2019

doi

10.1021/acssuschemeng.9b01903

Abstract

Herein, we describe the design and synthesis of novel pyridinium containing amide based poly(ionic liquid)s (PAPILs) for CO2 capture and separation. Additionally, a new and unique crystal structure of pyridinium containing diamine monomer [MDAP][TFSI] is also presented. PAPILs reveal potential for CO2/CH4 separation and isosteric heat of adsorption in the physisorption range.

First Page

10241

Last Page

10247

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