Abstract

In the current research, the mechanical and tribological behavior, and structural evolution of AA2124-3 and 5-wt.% graphene (G) composites prepared by a combination of ball milling and hot extrusion were investigated. Mixing followed by energy ball milling of the powders was conducted under argon atmosphere. Hot extrusion of the green compacts was carried out at 0.46 and 0.68 of the alloy melting temperature. Properties such as macro and micro-hardness, nanohardness, tensile and lattice strain were characterized. Wear rates, coefficient of friction (COF) were characterized using dry pin-on-disc test under loads of 50, 100N and 150N. Nanoscratch testing were employed to investigate the self-lubricating tribological behavior. X-ray diffraction, optical and scanning electron microscopy were used to determine the influence of the G-content on the crystallite size variation and the lattice strain for the ball milled powders compared to the hot extruded rods. Density measurements and optical microscopy (OM) were employed to investigate the consolidation degree and porosity variation as a function of increasing G- of the G and Al-matrices for the variable conditions. Bulk texture variation was analyzed to evaluate the influence of the extrusion temperature. AA 2124-3 wt.% G composites displayed the highest tensile properties, highest hardness and lowest wear rates and COF, as well as lowest scratch width and depth compared to the 5 wt.%G and the plain alloy. The uniform distribution of the G-particles within the Al-matrices for the 3wt.% containing composites hindered grain coarsening by the induced lattice strain compared to that of 5 wt% G ones. Moreover, addition of 3 wt.% G smeared thin uniform tribofilm on the surfaces of the worn composite rods. The formed layer reduced friction and wear. Increasing the G content up to 5 wt.% resulted in segregation and clustering of the G-particles within the Al-matrices, which caused microplouging and sever plastic deformation wear mechanism and excessive delamination. IV Lower consolidation temperatures of 300oC produced composites with lower wear rates due to the excessive strain hardening effect. Extrusion at 300oC produced a continuous G-encapsulating layer around the Al-matrix compared to an interrupted G-layer for the 450oC extrusions. The G-layer morphology influenced the dominating mechanism of the composite during deformation. Texture analysis of the AA2124-3 wt.%G extruded at low and high temperatures proved that both the Cu-and Shear are the dominating texture components, while increased texture intensities from 1.2-to-1.76 occurred with increasing the extrusion temperature.

Department

Nanotechnology Program

Degree Name

MS in Nanotechnology

Date of Award

6-1-2017

Online Submission Date

May 2017

First Advisor

Salem, Hanadi

Committee Member 1

Esawi, Amal

Committee Member 2

Abd El-Hamid, Ahmed Abd E-Moneim

Document Type

Thesis

Extent

128 p.

Rights

The author retains all rights with regard to copyright. The author certifies that written permission from the owner(s) of third-party copyrighted matter included in the thesis, dissertation, paper, or record of study has been obtained. The author further certifies that IRB approval has been obtained for this thesis, or that IRB approval is not necessary for this thesis. Insofar as this thesis, dissertation, paper, or record of study is an educational record as defined in the Family Educational Rights and Privacy Act (FERPA) (20 USC 1232g), the author has granted consent to disclosure of it to anyone who requests a copy.

IRB

Not necessary for this item

Comments

-Youssef Jameel Science and Technology Research Center members (YJSTRC) - ASRT : Academy of Scientific research and technology.

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