Ternary Ti-Mo-Fe Nanotubes as Efficient Photoanodes for Solar-Assisted Water Splitting
American University in Cairo
Energy Materials Laboratory
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Journal of Physical Chemistry C
Designing efficient and stable water splitting photocatalysts is an intriguing challenge for energy conversion systems. We report on the optimal fabrication of perfectly aligned nanotubes on trimetallic Ti-Mo-Fe alloy with different compositions prepared via the combination of metallurgical control and facile electrochemical anodization in organic media. The X-ray diffraction (XRD) patterns revealed the presence of composite oxides of anatase TiO2and magnetite Fe3O4with better stability and crystallinity. With the optimal alloy composition Ti-(5.0 atom %) Mo-(5.0 atom %) Fe anodized for 16 h, enhanced conductivity, improved photocatalytic performance, and remarkable stability were achieved in comparison with Ti-(3.0 atom %) Mo-(1.0 atom %) Fe samples. Such optimized nanotube films attained an enhanced photocatalytic activity of ∼0.272 mA/cm2at 0.9 VSCE, which is approximately 4 times compared to the bare TiO2nanotubes fabricated under the same conditions (∼0.041 mA/cm2at 0.9 VSCE). That was mainly correlated with the emergence of Mo and Fe impurities within the lattice, providing excess charge carriers. Meanwhile, the nanotubes showed outstanding stability with a longer electron lifetime. Moreover, carrier density variations, lower charge transfer resistance, and charge carriers dynamics features were demonstrated via the Mott-Schottky and electrochemical impedance analyses.
(2021). Ternary Ti-Mo-Fe Nanotubes as Efficient Photoanodes for Solar-Assisted Water Splitting. Journal of Physical Chemistry C, 125(23), 12504–12517.
Elbanna, Abdussalam M., et al.
"Ternary Ti-Mo-Fe Nanotubes as Efficient Photoanodes for Solar-Assisted Water Splitting." Journal of Physical Chemistry C, vol. 125,no. 23, 2021, pp. 12504–12517.